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Deaeration Steam and  water Quality V.Ganapathy

Dearation steam quantity in steam plants is influenced by several variables such as the amount of condensate returns,temperature,deaearator pressure and by feed water and boiler water quality. Figure below shows a boiler where a certain amount of steam taken for process is returned as condensate.
M,C,F,B and D are the make up water flow,condensate returns,feed water flow,blow down and deaeration steam ,all in lb/h.The calculation procedure for deaeration steam is illustrated by an example.

Example:A boiler generates 50,000 lb/h of saturated steam at 300 psia,out of which 10,000 lb/h is returned to the deaerator as condensate at 180 F.The rest is used in process.Make up water enters at 70F and steam at 300 psia is used for deaeration.The boiler drum water has a total dissolved solids(TDS) of 1500 ppm. The deaerator operates at 25 psia. The blow down also has a TDS of 1500 ppm,while the make up water has a TDS of 100 ppm.

Solution:From mass balance around the deaerator:
10,000+D+M=F=50,000+B             (1)
From energy balance around deaerator:
10,000x148+1202.8xD+Mx38=209xF=209x(50,000+B)         (2)
where 148,1202.8,38 and 209 are the enthalpies of condensate,boiler steam, make up water and feed water respectively in btu/lb. These values are from steam tables.
From balance of total dissolved solids in the system:
100xM=1500xB    or     M=15B         (3)
In this equation,we are neglecting the TDS of condensate,which is as good as steam and for practical purposes, negligible,as steam has a low level of TDS,typically 0.5 to 1 ppm..
There are three unknowns and three equations. From (1),
D+M=40,000 +B       (4)
Substituting (3) into (4),
D+15B=40,000+B or D+14B=40,000           (5)
From (2)
1,480,000+1202.8D+38x15B=209x50,000+209B        (6)
Solving (5) and (6) we have:
B=2375,D=6750,M=35,625 and F=52,375 lb/h. Considering vent steam and other heat losses,the value of D may be increased by 1 to 3 % for design purposes.
It is seen that the boiler water quality and feed water quality play a dominant role in deaeration steam evaluation. Larger the make up or higher the boiler water TDS,more the deaeration steam.Blow down losses also will be high.Boiler water quality is often maintained at levels suggested by either ABMA or ASME guidelines on boiler water. Table below is an extract from these guidelines.

Table:  Recommended Boiler water quality
drum press,psig per ASME per ABMA
0-300 <3500(mmho/cm) 700-3500(ppm)
301-450 <3000 600-3000
451-600 <2500 500-2500
601-750 <2000 200-1000
751-900 <1500 150-750
901-1000 <1000 125-625

Note that per ASME,the boiler water TDS is mentioned as specific conductance in micro mhos/cm,while the ABMA mentions the water quality in ppm. The relation between the two is about 0.45-0.5. That is, 1000 ppm=2000 mmho/cm.It can be seen that at lower steam pressures,up to 600 psig,the ASME is more stringent than the ABMA. Also,one may maintain the boiler water at lower levels than recommended and reduce the blow down.The drum internals has to be sized for achieving the desired steam purity based on boiler water quality. A few plants also operate at higher than recommended water quality. This affects not only the blow down quantity,which is a waste of energy,but also the performance of the drum internals and steam purity. In plants with superheaters,one has to be concerned with steam purity levels in addition to blow down water flow due to formation of deposits and assocated tube failure concerns. Investment in good feed water quality and drum internals goes a long way in reducing overall plant operating costs and maintenance downtime. Also,demineralized feed water is recommended if the feed water is used in spray attemperator for steam temperature control.

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